GCSE Combined Science revision · Chemistry: organic, analysis, atmosphere and resources

Crude oil, alkanes and cracking

The idea

Crude oil is a mixture of hydrocarbons, mostly alkanes (general formula CₙH₂ₙ₊₂: methane, ethane, propane, butane). Fractional distillation separates it into fractions with similar boiling points. As chain length increases, boiling point and viscosity increase and flammability decreases. Complete combustion gives carbon dioxide and water. Cracking breaks long-chain hydrocarbons into shorter, more useful alkanes and alkenes, using a catalyst or steam. Alkenes turn bromine water from orange to colourless.

  1. Use CₙH₂ₙ₊₂ for alkanes.
  2. Link chain length to properties.
  3. Write cracking equations with atoms balanced.

Watch out Cracking is needed because there is more demand for short-chain fuels than crude oil supplies.

See it worked

Worked example

Decane, C₁₀H₂₂, is cracked into octane, C₈H₁₈, and one other product. Find it.

  1. Carbon: 10 − 8 = 2; hydrogen: 22 − 18 = 4.
  2. C₂H₄ is ethene, an alkene.

Answer Ethene, C₂H₄

Your turn

Question 1Calculator allowed1 mark

What is the formula of propane?

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Question 2Calculator allowed1 mark

What is the test for an alkene?

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Question 3Calculator allowed1 mark

How many hydrogen atoms are in an alkane with 6 carbon atoms?

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Independent practice for AQA GCSE Combined Science: Trilogy (8464), not endorsed by AQA.

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